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OMG GUYS... What about Jun Mizutani.???
Okay, lots of greats. Liu Gouliang was definitely known for how he could dominate with his serves. Zhang Jike's serves are great. Ma Lin's are too. Werner Schlager would never have got through the Chinese team to win a World Championship without being able to dominate with his serves. His serves are pretty much as good as it gets. But I have to put in a plug for the most unlikely candidate:
He Zhi Wen:
This video should be called: "Dancing Lessons with He Zhi Wen"!
One more player which has really good serves is Pär Gerell. He seems to have worked very hard on this and in recent games many opponents had massive problems with his serves..